This volume is a collection of papers presented at the XIII International Workshop on Real and Complex Singularities, held from July 27–August 8, 2014, in São Carlos, Brazil, in honor of María del Carmen Romero Fuster's 60th birthday. The volume contains the notes from two mini-courses taught during the workshop: on intersection homology by J.-P. Brasselet, and on non-isolated hypersurface singularities and Lê cycles by D. Massey. The remaining contributions are research articles which cover topics from the foundations of singularity theory (including classification theory and invariants) to topology of singular spaces (links of singularities and semi-algebraic sets), as well as applications to topology (cobordism and Lefschetz fibrations), dynamical systems (Morse-Bott functions) and differential geometry (affine geometry, Gauss-maps, caustics, frontals and non-Euclidean geometries). This book is published in cooperation with Real Sociedad Matemática Española (RSME)